Numbers Chapter 13, Verse 22
From BibleWiki
22: And they ascended by the south, and came unto Hebron; where Ahiman, Sheshai, and Talmai, the children of Anak, were. (Now Hebron was built seven years before Zoan in Egypt.)
22: And when they were gone up, they viewed the land from the desert
of Sin, unto Rohob as you enter into Emath.
22: And they went up by the wilderness, and departed as far as Chebron; and there [was] Achiman, and Sessi, and Thelami, the progeny of Enach. Now Chebron was built seven years before Tanin of Egypt.
Numbers Chapter 13, Verse 22/commentary

